Experimental research on dynamic response of PZT-5H under impact load

In order to improve the stability of PZT-based sensors, the mechanical, dielectric, ferroelectric and piezoelectric properties of PZT-5H under impact load were studied experimentally by using the separated Hopkinson pressure bar (SHPB) with an electrical output measurement device. At the same time, the experimental study on the material properties of PZT-5H before and after the impact was carried out. The effect of impact cracks on the output voltage of PZT-5H was also analyzed. The results show that the dynamic piezoelectric constants of PZT-5H under low stress impact (10–50 MPa) are different from those under quasi-static state, and the empirical relationship between them and the peak stress is obtained through experiments. The dielectric properties of PZT-5H did not change under low stress impact, but micro-cracks occurred in the material and dielectric loss increased at high frequencies. Under short circuit, the residual polarization intensity of PZT-5H decreases sharply due to impact load. While the impact load causes the secondary polarization and the increase of the residual polarization intensity of PZT under open circuit. When the stress is over 45 MPa, the PZT-5H breaks. The formation of cracks causes abnormal discharge voltage and gap discharge.     

含煤盆地深层“超饱和”煤层气形成条件

中国深层煤层气资源丰富，但总体勘探和认识程度较低，尚未形成较为系统的深层煤层气地质理论。通过解剖分析准噶尔盆地白家海凸起和鄂尔多斯盆地临兴区块深层"超饱和"煤层气井的试气/生产动态，估算原地游离气的含气量，分析了深层"超饱和"煤层气的形成条件。研究表明：①深层"超饱和"煤层气储层中除吸附气外，还含有原地游离气，用常规试气方法可直接获得气流，煤层气的产出不明显依赖于排水降压；②埋藏超过一定深度，在煤阶和温度的综合作用下，煤的吸附能力将随埋深的继续增加而降低，煤层中吸附气的饱和度有增加的趋势，在达到吸附饱和后，出现原地游离气并形成"超饱和"煤层气，盆地深层具有"超饱和"煤层气形成的优势条件；③由于地温梯度和压力梯度的不同，不同盆地"超饱和"煤层气出现的临界深度不同，异常高压和异常高热流可以降低深层"超饱和"煤层气形成的临界深度；④深层"超饱和"煤层气开发具有大大缩短见气时间、充分利用地层能量和累积产水量低等优势，有望成为未来煤层气勘探开发的一个重要领域。     

不同煤阶煤孔隙特征及其吸附能力响应

我国是煤炭资源大国，煤层气储量规模相当可观，但煤储层又具有低孔、低渗的不足，照搬国外或常规石油天然气的开采程序和方法已被证实是走不通的。应结合实际，根据不同地质条件、不同煤阶的开采程序，进行孔隙特征研究。煤孔隙特征、连通性和吸附能力对煤层气开采影响尤为重要，为研究煤孔隙结构特征随煤变质程度的变化关系及其吸附能力的响应特点，采取不同地区不同变质程度煤样，进行压汞测试和等温吸附实验。实验结果表明，煤孔隙度和平均孔径均随变质程度增加呈现降低—升高—降低的趋势；煤中孔隙连通性随煤变质程度增加逐渐变差；随煤变质程度增加，其最大吸附能力也呈现降低—升高—降低的总体趋势。     

福建某低品位金矿新型浸金剂浸金试验

福建某斑岩型金矿品位低、规模大,金主要以自然金形式存在,可见金的粒度较粗,为高效利用该低品位金矿,开展新型浸金剂金蝉全泥浸出试验和柱浸试验,结果表明：全泥浸出在磨矿细度为-0.074 mm占80%、矿浆浓度25%、加石灰调pH 值11.0左右、初始金蝉浓度为500 mg/L和过程中控制金蝉浓度不小于300 mg/L条件下浸出20 h,金的浸出率为93.43%,金蝉耗量为1.02 kg/t；柱浸在矿石粒度为-30 mm条件下喷淋浸出23天,金累计浸出率和金蝉累计耗量分别为86.54%和1.22 kg/t。     

Structural,electrical, optical and dielectric properties of yttrium substituted cadmium ferrites prepared by Co-Precipitation method

The yttrium substituted cadmium ferrites having composition Cd_1-xY_xFe₂O₄ (X = 0.00, 0.125, 0.250, 0.375, 0.500) were synthesized by the co-precipitation method and sintered at 1100 °C for 6 h. Structural, morphological, electrical, optical and dielectric characteristics were explored by XRD, SEM, EDS, FTIR, I–V two probes, UV–Vis and LCR techniques.XRD results confirmed the cubic structure of spinel ferrites. A decrease in lattice constants of the prepared samples was observed with the substitution of Y ions and was attributed to the difference in ionic radii of Y³⁺ (0.95 Å) and Cd²⁺ (0.97 Å) ions. Cationic distributions, ionic radii of both tetrahedral and octahedral sites, tolerance factor, oxygen positional parameters, bond lengths, interatomic distances, positional parameters and bond length angles were calculated from XRD data. The morphology of the prepared ferrites was studied using SEM and results ratified the XRD results. EDS confirmed the presence of all inserted elements in Cd_1-xY_xFe₂O₄ composition. DC resistivity and drift mobility of soft-ferrites were found to be increased from 1.047 × 10⁸–4.822 × 10¹⁰ Ω-cm and 5.87 × 10⁻¹² – 1.045 × 10⁻¹⁴ cm²V⁻¹s⁻¹, respectively, at 523 K with yttrium content confirming the behavior of semiconductor materials. The optical band gap energy calculated from the UV–Vis pattern of the Cd_1-xY_xFe₂O₄ system was decreased from 3.6011 to 2.8153 eV. DC resistivity and optical band gaps exposed inverse relation. FTIR results revealed lower and upper-frequency absorption bands in the ranges of 419.31–417.01 cm⁻¹ and 540.95–565.70 cm⁻¹, respectively. Dielectric constant and dielectric losses were in decreasing order, while ac conductivity revealed rising behavior with increasing frequency. Results showed the potential of yttrium doped Cd nanoferrites for applications in high-frequency microwave absorbing devices.     

55SiCr弹簧钢中的残留奥氏体与碳化物

通过扫描电镜(SEM)、电子背散射衍射(EBSD)、透射电镜(TEM)、X射线衍射仪(XRD)、热膨胀仪、洛氏硬度计等手段研究了弹簧钢55SiCr的组织和相变点以及残留奥氏体和碳化物在热处理过程中的组织演变。结果表明:55SiCr弹簧钢淬火后残留奥氏体以块状分布在基体上;随回火温度的升高,残留奥氏体减少并呈粒状和薄膜状分布;C在残留奥氏体中富集,使其稳定性增强;Si抑制了碳化物的析出,提高了残留奥氏体的稳定性。低温回火时,Si延缓了渗碳体析出;高温回火时,C原子扩散速率提高,促进渗碳体析出,引起体积的收缩。慢速加热回火时,C有足够的时间扩散,从而促进渗碳体的形成,使渗碳体的形成温度提前;快速加热回火时,C来不及扩散,抑制了渗碳体的析出。回火加热速率一样时,试验钢的硬度随回火温度的提高而下降。当回火温度为400 ℃时,硬度值最大为51 HRC;当回火温度为650 ℃时,硬度值最小为37 HRC。当加热速率为0.1 ℃/s时,硬度值最小为33 HRC;当加热速率为200 ℃/s时,硬度值最大为40 HRC。     

内嵌纳凝胶阴离子交换聚甲基丙烯酸羟乙酯复合晶胶分离苯乳酸研究

采用超声乳化聚合法制备了聚甲基丙烯酸丁酯纳凝胶，然后经结晶致孔法制备了内嵌纳凝胶的甲基丙烯酸羟乙酯纳晶胶，对其接枝功能单体N，N，N-三甲基乙烯基苯甲氯化铵，得到内嵌纳凝胶阴离子交换纳晶胶，用于从发酵液中分离苯乳酸。结果表明：所得纳晶胶具有良好的渗透性能和轴向分散性能，在流速为1 cm·min^-1时，不同配比纳晶胶对牛血清白蛋白的吸附容量为3.9~5.4 mg·ml^-1；将质量比为 8∶2（HEMA∶pBMA）的纳晶胶用于从转化液中分离苯乳酸，所得苯乳酸的纯度达89.24%，回收率93.74%，分离效果好，表明其在生物分离方面有良好的应用前景。     

Tribological behaviour of a 3Y-TZP/Ta ceramic-metal biocomposite against ultrahigh molecular weight polyethylene (UHMWPE)

This study aims to evaluate the tribological behaviour of 3Y-TZP/Ta (20 vol%) ceramic-metal composites and 3Y-TZP monolithic ceramic prepared by spark plasma sintering (SPS) against ultrahigh molecular weight polyethylene (UHMWPE). According to the results of pin (UHMWPE)-on-flat wear test under dry conditions, the UHMWPE – 3Y-TZP/Ta system exhibited lower volume loss and friction coefficient than the UHMWPE – monolithic ceramic combination due to the presence of an autolubricating layer that provides sufficient lubrication for reducing the friction. Owing to the lubrication of the liquid media, under wet conditions obtained using simulated body fluid (SBF), similar behaviour is observed in both cases. Additionally, the ceramic and biocomposite materials were subjected to a low temperature degradation (LTD) process (often referred to as “ageing”) to evaluate the changes in the tribological behaviour after this treatment. In this particular case, the wear properties of the UHMWPE-biocomposite system were found to be less influenced by ageing in contrast to the case of the UHMWPE-zirconia monolithic material. In addition to their exceptional mechanical performance, 3Y-TZP/Ta composites also showed high resistance to low temperature degradation and good tribological properties, making them promising candidates for biomedical applications, especially for orthopaedic implants.